Helically Chiral Mixed-Valence Systems Comprising N-Heterotriangulenes: Stabilization of the Cationic Species by π-Expansion

We report the efficient stabilization of nitrogen-centered radical cations in a dimeric N-heterotriangulene bridged by a rigid π-conjugated [5]helicene backbone (NTH). The rigid scaffold exhibits helical chirality, allowing the enantiomers to be separated and their chiroptical properties studied, including circular dichroism (CD) and circularly polarized luminescence (CPL). Successive oxidation towards the radical cation NTH•+ and dication NTH2+ reveals strong electronic communication …